A biomass-based hierarchical carbon via MOFs-assisted synthesis for high-rate lithium-ion storage

Ronggang Zhang; Qing Hou; Yanhong Wang; Weixiang Zhu; Jingmin Fan; Mingsen Zheng; Quanfeng Dong

Electrochemistry Communications (Jun 2022)

A biomass-based hierarchical carbon via MOFs-assisted synthesis for high-rate lithium-ion storage

Ronggang Zhang,
Qing Hou,
Yanhong Wang,
Weixiang Zhu,
Jingmin Fan,
Mingsen Zheng,
Quanfeng Dong

Affiliations

Ronggang Zhang: Electronic and Mechanical Engineering, Fujian Polytechnic Normal University, Fuzhou, China; Corresponding authors at: Electronic and Mechanical Engineering, Fujian Polytechnic Normal University, Fuzhou, China (R. Zhang). State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (i-ChEM), Engineering Research Centre of Electrochemical Technologies of Ministry of Education, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, 361005 Xiamen, China (J. Fan and Q. Dong).
Qing Hou: State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (i-ChEM), Engineering Research Centre of Electrochemical Technologies of Ministry of Education, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, 361005 Xiamen, China
Yanhong Wang: State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (i-ChEM), Engineering Research Centre of Electrochemical Technologies of Ministry of Education, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, 361005 Xiamen, China; Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen, China
Weixiang Zhu: State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (i-ChEM), Engineering Research Centre of Electrochemical Technologies of Ministry of Education, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, 361005 Xiamen, China; Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen, China
Jingmin Fan: State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (i-ChEM), Engineering Research Centre of Electrochemical Technologies of Ministry of Education, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, 361005 Xiamen, China; Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen, China; Corresponding authors at: Electronic and Mechanical Engineering, Fujian Polytechnic Normal University, Fuzhou, China (R. Zhang). State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (i-ChEM), Engineering Research Centre of Electrochemical Technologies of Ministry of Education, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, 361005 Xiamen, China (J. Fan and Q. Dong).
Mingsen Zheng: State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (i-ChEM), Engineering Research Centre of Electrochemical Technologies of Ministry of Education, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, 361005 Xiamen, China; Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen, China
Quanfeng Dong: State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (i-ChEM), Engineering Research Centre of Electrochemical Technologies of Ministry of Education, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, 361005 Xiamen, China; Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen, China; Corresponding authors at: Electronic and Mechanical Engineering, Fujian Polytechnic Normal University, Fuzhou, China (R. Zhang). State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (i-ChEM), Engineering Research Centre of Electrochemical Technologies of Ministry of Education, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, 361005 Xiamen, China (J. Fan and Q. Dong).

Journal volume & issue: Vol. 139
p. 107310

Abstract

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A hierarchical nanostructured biomass-based carbon material derived from banana peels slurry and ZIF-8 hybrids (HNBZC) is introduced with excellent lithium-ion storage and rate capability. HNBZC was prepared through a hollow MOFs-assisted hard template strategy, in which we can easily control the pore size and doping element content to further improve the electrochemical performance of biomass-based carbon. HNBZC can reversibly deliver a capacity of 620 mAh g−1 at current densities of 20 mA g−1, and 61 mAh g−1 is still obtained at a high current density of 50 A g−1. Furthermore, a capacity retention ratio of 80% is achieved after 780 cycles at 5 A g−1. Our results indicate a promising method to obtain a carbon material with enhanced electrochemical performance based on natural biomass waste.

Published in Electrochemistry Communications

ISSN: 1388-2481 (Print); 1873-1902 (Online)
Publisher: Elsevier
Country of publisher: United States
LCC subjects: Technology: Chemical technology: Industrial electrochemistry; Science: Chemistry
Website: https://www.journals.elsevier.com/electrochemistry-communications

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