Acta Crystallographica Section E (Nov 2008)
catena-Poly[[[aqua(pyridine-2,6-dicarboxylato N-oxide-κ2O1,O2)cobalt(II)]-μ-1,3-di-4-pyridylpropane-κ2N:N′] dihydrate]
Abstract
In the title compound, {[Co(C7H3NO5)(C13H14N2)(H2O)]·2H2O}n, the CoII atom is coordinated by two O atoms from a pyridine-2,6-dicarboxylate N-oxide ligand, two N atoms from two 1,3-di-4-pyridylpropane ligands and one water molecule, and displays a distorted square-pyramidal coordination geometry. The 1,3-di-4-pyridylpropane ligands link the CoII atoms into an infinite zigzag chain parallel to [010]. The chains are further linked through O—H...O and C—H...O hydrogen bonds, forming a three-dimensional supramolecular network.