Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ (May 2016)

SYNTHESIS, THERMAL STABILITY AND STRUCTURE OF TIN(IV) COMPLEXES WITH AROMATIC ALDEHYDES BENZOYL-(SALICYLOYL)HYDRAZONES

  • N. V. Shmatkova,
  • G. V. Yalovskiy,
  • I. I. Seifullina,
  • S. E. Samburskii

DOI
https://doi.org/10.18524/2304-0947.2008.12.68549
Journal volume & issue
Vol. 13, no. 12
pp. 65 – 72

Abstract

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The complexes of composition [SnCl3L]nCH3CN (n=0—2) have been obtained by SnCl4 interaction with 2-hydroxy(benz)-1-naphthaldehydes benzoyl-(salicyloyl)hydrazones in acetonitrile. It was proved by methods of electronic, IR- and PMR spectroscopy ligands molecules to be coordinated by tin atom as tridentate ones via azomethine group nitrogen atom and carbonyl and oxy-groups oxygen atoms. The thermal stability of obtained compounds has been studied. The structure schemes are offered.

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