Materials Research (May 2024)

Superhydrophobic Surfaces Based on Nickel Stearate: An Innovative Approach to Coatings on 7050 Aeronautical Aluminum Alloy

  • Jedaías J. da Silva,
  • Ana L. C. Guimarães,
  • Walter L. C. da Silva Filho,
  • Rafael G. C. da Silva,
  • Maria I. C. Malta,
  • Dayanne D. S. Morais,
  • Severino L. Urtiga Filho,
  • Magda R. S. Vieira

DOI
https://doi.org/10.1590/1980-5373-mr-2023-0562
Journal volume & issue
Vol. 27, no. suppl 1

Abstract

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A metallic surface can exhibit low wettability through the formation of a rough structure with micro/nanometric dimensions combined with a surface energy-reducing agent. When the contact and sliding angles are ≥ 150° and ≤ 10°, respectively, the surface is classified as superhydrophobic (SHS). The study aimed to electrodeposit a microstructure with micronanometric roughness of nickel, stearic acid (Al/Ni-SA), and nickel, stearic acid with multi-layered carbon nanotubes (Al/Ni-SA-MWCNT) on aeronautical aluminum 7050. The obtained contact angles were close to 160°, and sliding angles were less than 1°, characterizing the superhydrophobic and self-cleaning nature. Freezing tests were conducted, and the deposit with MWCNT showed longer freezing times at -22°C. The Al/Ni-SA-MWCNT condition also exhibited the best corrosion resistance with corrosion current superior by two orders of magnitude compared to the Al/Ni-Sa condition. The coatings demonstrated impressive performance, achieving corrosion inhibition efficiencies close to 100%.

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