Because it’s physical properties, ZnO is considered a potential semiconductor compound for fabricating electronic and optoelectronic functional devices. In this regard, several growth techniques have been developed in order to meet the requirements of commercial devices based in this material. On the pathway for improving the performance of the current devices, low-dimensional ZnO structures seem a promising alternative. Here, we report the process to obtain a metal-insulator-semiconductor (MIS) structure based on ZnO nanostructures grown on the surface of an anodized aluminum substrate (Al2O3/Al) by chemical routes.