With the development of underwater exploration, underwater networking is in urgent demand. At present, underwater wireless optical communication (UWOC) is primarily based on line-of-sight (LOS) communication links. However, the underwater environment is so complicated that LOS communication links are easily affected by a couple of factors such as air bubbles, turbidity, oceanic turbulence, and so on. We put forward novel UWOC links using the total reflection at the air-water interface, which can mitigate those phenomena. This paper aims to investigate a UWOC link based on the total reflection at the air-water interface. In our work, we achieved the maximum data rate of 300 Mb/s and a bit error rate (BER) of 3.10 × 10−3 under the forward error correction (FEC) with the total reflection angle of 7°. Furthermore, we verified the performance of the total reflection-based UWOC links at the air-water interface in the presence of waves and evaluated the impact on the UWOC links when the frequency and amplitude of the waves varied.