Sustainable catalytic pathways for biofuel precursors: quantitative conversion of glucose to gluconic acid using Pt-Zn biochar catalyst

Abstract

Achieving quantitative conversion of biomass-derived feedstocks under ambient environmental conditions (20°C, atmospheric air, 0.1 MPa) is a critical milestone for sustainability in chemical processes. Herein, the quantitative conversion of glucose to gluconic acid was accomplished under ambient environmental conditions without any additives using a Pt-Zn intermetallic nanoparticle-supported biochar catalyst prepared from raw rice straw (Pt-Zn/strawC) via a straightforward one-pot solvothermal reaction with ethylene glycol solvent. Spectroscopic analyses verified the formation of the Pt-Zn intermetallic alloy and confirmed strong electronic metal-support interactions. The Pt-Zn/strawC catalyst (Pt:Zn molar ratio of 1:6) was highly selective for the conversion of glucose to gluconic acid, whereas yields as high as 99.9% (98.9% gluconic acid, 1.0% glucaric acid) were reached at 20 oC under base-free and additive-free conditions. Isotope measurements and density functional theory revealed synergistic interactions in the Pt-Zn alloy, wherein the alloy tended to absorb glucose and active O2 into superoxide radical (O2·). This work demonstrates a chemocatalytic method that is practical for environmental conditions and provides a new avenue for sustainable conversion of lignocellulosic biomass to chemical products.

Keywords

• biomass
• pt-zn alloy
• biochar
• solvothermal synthesis
• one-pot reaction
• sugar acid