Atmosphere (Nov 2024)

Characterization of the Elemental Composition of Aerosols Emitted in the Dry Season of the Pantanal Wetland, Brazil

  • Lucas Cardoso Ramos,
  • Thais Costa Brunelli,
  • Flávio César Vicentin,
  • Leone Francisco Amorim Curado,
  • André Matheus de Souza Lima,
  • Fernando Gonçalves Morais,
  • Rafael da Silva Palácios,
  • Nicolas Neves de Oliveira,
  • João Basso Marques

DOI
https://doi.org/10.3390/atmos15111361
Journal volume & issue
Vol. 15, no. 11
p. 1361

Abstract

Read online

The Brazilian Pantanal region experiences intense biomass burning during the dry season, releasing large quantities of gasses and particles into the atmosphere, which have serious implications on both the climate system and public health. Understanding the dynamics of these emissions is crucial for mitigating the impact on the ecosystem, its functioning, and potential anthropogenic disturbances. This study focused on analyzing emissions in the northern Pantanal during the 2022 drought. Concentrations of fine particulate matter (PM2.5), black carbon (BC), and 25 chemical elements were measured using gravimetry, reflectance analysis, and X-Ray fluorescence, respectively, from samples collected between August and October 2022. The average concentrations of PM2.5 and BC increased approximately 4-fold and 2.5-fold, respectively, compared to averages from a decade ago. Significant increases were also observed in elements such as sulfur (S), potassium (K), iron (Fe), and silicon (Si). The maximum concentrations were comparable to values typical of the southern Amazon, a region known for high deforestation rates and land use changes. Elemental analysis revealed substantial shifts in concentrations, primarily associated with biomass burning (BB) and soil suspension. Additionally, enrichment factor (Ef) analysis showed that lead (Pb) levels, correlated with human activities, were 200 times higher than those found under clean atmospheric conditions.

Keywords