Mineralogical studies are incipient and necessary in the Apodi Plateau, Brazil. This study aimed to evaluate the interrelationship between the mineralogy of the clay fraction and its structural and chemical attributes and to differentiate two important pedo-environments in the semi-arid region of northeastern Brazil (Ferralsol and Cambisols of the Apodi Plateau-RN) using the multivariate technique. We evaluated the interrelationships between mineralogy and the structural and chemical attributes of the soil and differentiated between agroenvironments. We collected soil samples from six profiles in diagnostic horizons of the Ferralsols and Cambisols. In the mineralogical analysis of the clay fraction, X-Ray Diffraction was used to identify mineral peaks of clay and iron oxides. The physical and chemical properties of the soils were determined. The multivariate statistical technique was applied to process the data. The clay minerals identified were hematite, goethite, kaolinite, and illite. The principal component analysis allowed for the separation of environments according to soil density, Fed and Mg2+ for developed soils, and potassium, weighted average diameter, microporosity, total organic carbon, sodium, the sum of bases, calcium, total porosity, aeration, potential acidity, and Feo discriminated developing soils. This study revealed that the clay fraction influenced the structural attributes of the soil according to the degree of soil development. Two profiles presented atypical situations: High contents of crystallized iron in Cambisols and illite peaks in Ferralsolos. These mineralogical results are not commonly found in the literature, highlighting the potential for further studies. The answers concerning the mineralogy of semiarid soils in Brazil and the world show similarity.
