IUCrData (Feb 2021)

Di-μ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvate

  • Abdul-Razak H. Al-Sudani,
  • Myasim Qasim Abdulridha,
  • Benson M. Kariuki

DOI
https://doi.org/10.1107/S2414314621001504
Journal volume & issue
Vol. 6, no. 2
p. x210150

Abstract

Read online

The title solvated bimetallic complex, [Cd2Cl4(C13H17N3)2]·C2H5OH, comprises two Cd2+ metal ions linked by a pair of μ2 Cl− ions. The coordination sphere around each Cd2+ ion is completed by three N atoms of a tridentate 8-[2-(dimethylamino)ethylamino]quinoline ligand and another chloride ion to form a distorted fac-CdN3Cl3 octahedron. The ethanol molecule is both an acceptor of an N—H...O and a donor of an O—H...Cl hydrogen bonds to its adjacent complex unit. In the crystal, weak aromatic π–π stacking is observed.

Keywords