Quartz-enhanced multiheterodyne resonant photoacoustic spectroscopy

Abstract

Abstract The extension of dual-comb spectroscopy (DCS) to all wavelengths of light along with its ability to provide ultra-large dynamic range and ultra-high spectral resolution, renders it extremely useful for a diverse array of applications in physics, chemistry, atmospheric science, space science, as well as medical applications. In this work, we report on an innovative technique of quartz-enhanced multiheterodyne resonant photoacoustic spectroscopy (QEMR-PAS), in which the beat frequency response from a dual comb is frequency down-converted into the audio frequency domain. In this way, gas molecules act as an optical-acoustic converter through the photoacoustic effect, generating heterodyne sound waves. Unlike conventional DCS, where the light wave is detected by a wavelength-dependent photoreceiver, QEMR-PAS employs a quartz tuning fork (QTF) as a high-Q sound transducer and works in conjunction with a phase-sensitive detector to extract the resonant sound component from the multiple heterodyne acoustic tones, resulting in a straightforward and low-cost hardware configuration. This novel QEMR-PAS technique enables wavelength-independent DCS detection for gas sensing, providing an unprecedented dynamic range of 63 dB, a remarkable spectral resolution of 43 MHz (or ~0.3 pm), and a prominent noise equivalent absorption of 5.99 × 10-6 cm-1·Hz-1/2.