Nature Communications (Feb 2022)
Ultrafast charge transfer dynamics in 2D covalent organic frameworks/Re-complex hybrid photocatalyst
- Qinying Pan,
- Mohamed Abdellah,
- Yuehan Cao,
- Weihua Lin,
- Yang Liu,
- Jie Meng,
- Quan Zhou,
- Qian Zhao,
- Xiaomei Yan,
- Zonglong Li,
- Hao Cui,
- Huili Cao,
- Wenting Fang,
- David Ackland Tanner,
- Mahmoud Abdel-Hafiez,
- Ying Zhou,
- Tonu Pullerits,
- Sophie E. Canton,
- Hong Xu,
- Kaibo Zheng
Affiliations
- Qinying Pan
- Department of Chemistry, Technical University of Denmark
- Mohamed Abdellah
- Chemical Physics and NanoLund, Lund University
- Yuehan Cao
- State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University
- Weihua Lin
- Chemical Physics and NanoLund, Lund University
- Yang Liu
- State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University
- Jie Meng
- Department of Chemistry, Technical University of Denmark
- Quan Zhou
- Department of Energy Conversion and Storage, Technical University of Denmark
- Qian Zhao
- Department of Chemistry, Technical University of Denmark
- Xiaomei Yan
- Department of Chemistry, Technical University of Denmark
- Zonglong Li
- Institute of Nuclear and New Energy Technology, Tsinghua University
- Hao Cui
- Institute of Nuclear and New Energy Technology, Tsinghua University
- Huili Cao
- Department of Chemistry, Technical University of Denmark
- Wenting Fang
- Department of Chemistry, Technical University of Denmark
- David Ackland Tanner
- Department of Chemistry, Technical University of Denmark
- Mahmoud Abdel-Hafiez
- Department of Physics and Astronomy, Uppsala University
- Ying Zhou
- State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University
- Tonu Pullerits
- Chemical Physics and NanoLund, Lund University
- Sophie E. Canton
- European XFEL
- Hong Xu
- Institute of Nuclear and New Energy Technology, Tsinghua University
- Kaibo Zheng
- Department of Chemistry, Technical University of Denmark
- DOI
- https://doi.org/10.1038/s41467-022-28409-2
- Journal volume & issue
-
Vol. 13,
no. 1
pp. 1 – 13
Abstract
Re complexes within covalent organic frameworks have emerged as promising photocatalysts for CO2 reduction. Here, authors identify a high-energy electron transfer pathway during CO2 reduction that results in longer-lived excited states than a low-energy electron transfer pathway.
