Strong metal-support interaction (SMSI) in environmental catalysis: Mechanisms, application, regulation strategies, and breakthroughs

Abstract

The strong metal-support interaction (SMSI) in supported catalysts plays a dominant role in catalytic degradation, upgrading, and remanufacturing of environmental pollutants. Previous studies have shown that SMSI is crucial in supported catalysts' activity and stability. However, for redox reactions catalyzed in environmental catalysis, the enhancement mechanism of SMSI-induced oxygen vacancy and electron transfer needs to be clarified. Additionally, the precise control of SMSI interface sites remains to be fully understood. Here we provide a systematic review of SMSI's catalytic mechanisms and control strategies in purifying gaseous pollutants, treating organic wastewater, and valorizing biomass solid waste. We explore the adsorption and activation mechanisms of SMSI in redox reactions by examining interfacial electron transfer, interfacial oxygen vacancy, and interfacial acidic sites. Furthermore, we develop a precise regulation strategy of SMSI from systematical perspectives of interface effect, crystal facet effect, size effect, guest ion doping, and modification effect. Importantly, we point out the drawbacks and breakthrough directions for SMSI regulation in environmental catalysis, including partial encapsulation strategy, size optimization strategy, interface oxygen vacancy strategy, and multi-component strategy. This review article provides the potential applications of SMSI and offers guidance for its controlled regulation in environmental catalysis.

Keywords

• Environmental catalysis
• Metal oxide supported catalysts
• Strong metal-support interaction (SMSI)
• Interfacial site regulation
• Electron transfer