Arabian Journal of Chemistry (Apr 2023)
Synthesis and plugging effect of inverse emulsion polymerization microspheres (OPME) for oil-based drilling fluids
Abstract
It is difficult to seal oil-based drilling fluids in the large pore and micro-fracture formation, and there are few suitable materials for the oil phase with good sealing ability at present. In order to solve the problem of the lack of sealing ability of oil-based drilling fluids, acrylamide, 2-acrylamido-2-methylpropane sulfonic acid, and acryloyl morpholine were used as monomers, N'N-methylenebisacrylamide was used as a cross-linking agent, Span-80 and Tween-60 were used as emulsifiers, and 2,2′-azobis(2-methylpropionamidine) dihydrochloride was used as an initiator. Polymer microsphere emulsion OPME was synthesized by inverse emulsion polymerization. The structure of polymer microspheres was characterized by infrared spectroscopy, scanning electron microscopy, electron microscopy, H NMR, laser particle size analysis and thermogravimetric analysis. The optimal synthesis conditions were determined by the control variable method: the monomer ratio of acrylamide, 2-acrylamido-2-methylpropane sulfonic acid, and acryloyl morpholine was 45:20:15, the amount of emulsifier was 8%, and the reaction temperature was 55℃. The synthetic polymer microspheres were added to the oil-based drilling fluids to perform filtration and loss plugging at atmospheric pressure and high-temperature and high-pressure, as well as pore and artificial fracture core plugging evaluation. The evaluation results show that the permeability reduction rate of pore core can reach 82%, and that of fracture core can reach 100% by adding polymer microspheres with 3% dosage. Finally, the pressure transmission experiment proves that the addition of polymer microspheres can slow the pressure transmission and filtrate intrusion, and enhance the stability of wellbore. Therefore, polymer microspheres are a micron-level plugging agent with good compatibility and high performance with oil-based drilling fluids, and the 3% dosage can better seal the formation of large pores and micro-fractures, which has a good potential for field application.
