Nano-Micro Letters (Sep 2024)
Molecule-Level Multiscale Design of Nonflammable Gel Polymer Electrolyte to Build Stable SEI/CEI for Lithium Metal Battery
- Qiqi Sun,
- Zelong Gong,
- Tao Zhang,
- Jiafeng Li,
- Xianli Zhu,
- Ruixiao Zhu,
- Lingxu Wang,
- Leyuan Ma,
- Xuehui Li,
- Miaofa Yuan,
- Zhiwei Zhang,
- Luyuan Zhang,
- Zhao Qian,
- Longwei Yin,
- Rajeev Ahuja,
- Chengxiang Wang
Affiliations
- Qiqi Sun
- Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University
- Zelong Gong
- Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University
- Tao Zhang
- Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University
- Jiafeng Li
- Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University
- Xianli Zhu
- Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University
- Ruixiao Zhu
- Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University
- Lingxu Wang
- Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University
- Leyuan Ma
- Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University
- Xuehui Li
- Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University
- Miaofa Yuan
- Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University
- Zhiwei Zhang
- Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University
- Luyuan Zhang
- Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University
- Zhao Qian
- Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University
- Longwei Yin
- Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University
- Rajeev Ahuja
- Condensed Matter Theory, Department of Physics and Astronomy, Uppsala University
- Chengxiang Wang
- Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University
- DOI
- https://doi.org/10.1007/s40820-024-01508-z
- Journal volume & issue
-
Vol. 17,
no. 1
pp. 1 – 20
Abstract
Highlights Nonflammable gel polymer electrolyte (SGPE) is developed by in situ polymerizing trifluoroethyl methacrylate (TFMA) monomers with flame-retardant triethyl phosphate (TEP) solvents and LiTFSI–LiDFOB dual lithium salts. Molecular polarity interaction between TEP and PTFMA mitigates interfacial reactions and changes the solvation of Li+. SGPE forms stable inorganic-rich solid electrolyte interface/cathode electrolyte interface layer, exhibiting well compatibility with Li anode and LiCoO2-type high-voltage cathode.
Keywords
- Anchoring effect
- Nonflammable gel electrolyte
- In situ cross-linked
- Electrode–electrolyte interface
- Li metal battery
