IUCrData (Aug 2023)

Tetrel bond in the triphenyltin(IV) chloride–cyclohexyldiphenylphosphane oxide (1/1) cocrystal

  • Sachin Liyanage,
  • Jeffrey S. Ovens,
  • David L. Bryce

DOI
https://doi.org/10.1107/S2414314623006375
Journal volume & issue
Vol. 8, no. 8
p. x230637

Abstract

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The single-crystal X-ray diffraction structure of the title compound, [SnCl(C6H5)3]·C18H21OP, is reported. The 1:1 cocrystal features a short and directional tetrel bond between tin and oxygen. The tin–oxygen distance is 2.346 (4) Å, representing 62% of the sum of the van der Waals radii of Sn and O. The Cl—Sn...O angle is 174.0 (1)° and this nearly linear arrangement is consistent with a tetrel bond formed via a σ-hole opposite the tin–chlorine covalent bond. Some weak C—H...Cl interactions are noted between adjacent molecules.

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