Acta Crystallographica Section E (May 2010)

Di-μ-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)]

  • Alexandra M. Z. Slawin,
  • Paul G. Waddell,
  • J. Derek Woollins

DOI
https://doi.org/10.1107/S1600536810012055
Journal volume & issue
Vol. 66, no. 5
pp. m499 – m499

Abstract

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The title compound, [Pd2Cl4(C8H11O2P)2], is binuclear and disposed about a crystallographic centre of symmetry with a Pd...Pd distance of 3.4662 (17) Å. It has a similar geometry to that observed in the triphenylphosphite and triphenylphosphine analogues. The Pd—P bond length is ca 0.04 Å shorter than those in mononuclear PdCl2(P(OMe)2Ph)2, possibly due to the lower trans-influence of the bridging Cl− compared to a single-bonded Cl− atom.