A chemical sensor was fabricated using indium-tin-oxide (ITO) films printed on biodegradable plastic substrates. The ITO layers were printed on polylactic acid (PLA) films. To optimize the printing procedure, the thermal properties of the PLA substrate were investigated using the differential scanning calorimetry method. The structural and electrical properties of the fabricated ITO films (P-ITO) were compared with commercial sputtered ITO films (S-ITO). X-ray diffraction and Hall effect measurements were used to estimate the grain size and the carrier transportation mechanism of the ITO films. The small grain size of P-ITO was attributed to its scattering mechanism. Grain boundary scattering was shown to be dominant in the P-ITO. The chemical sensing properties were also evaluated using a droplet of methanol (20 µl), indicating that the response rate of the P-ITO film was considerably higher (650%) than that of the S-ITO film. These results were attributed to the large surface area of the P-ITO film.
