Ethanol Electrooxidation on Phase- and Morphology-Controlled Ni(OH)₂ Microspheres

Abstract

The electrooxidation kinetics of ethanol is key to making direct ethanol fuel cells and electrocatalytically reforming ethanol viable technologies for a more sustainable energy conversion. In this study, the electrooxidation of ethanol was investigated on nickel hydroxide (Ni(OH)2) catalysts synthesized using a facile solvothermal method. Variations in the temperature, heating time, and the addition of oleylamine in the precursor enabled the phase and morphology control of the catalysts. X-ray diffraction and scanning electron microscopy show that the addition of oleylamine in the precursor resulted in microspheres with a high surface area, but favored the formation of β-phase Ni(OH)2. Elevated temperatures or prolonged periods of heating in a controlled environment, on the other hand, can lead to the formation of the ethanol oxidation reaction-active α-phase. Among the synthesized catalysts, the α-Ni(OH)2 microspheres with nanoflakes achieved the highest activity for ethanol oxidation with a current density of 24.4 mA cm−2 at 1.55 V (vs. RHE, reversible hydrogen electrode) in cyclic voltammetry tests and stable at 40 mA cm−2 in chronoamperometric tests at the same potential, comparatively higher than other Ni-based catalysts found in the literature. While the overpotential is beyond the useful range for direct ethanol fuel cells, it may be useful for understanding the mechanism of ethanol oxidation reactions on transition metal hydroxides at their oxidizing potential for ethanol electroreforming.

Keywords

• ethanol electrooxidation
• nickel hydroxide
• direct ethanol fuel cells
• electrocatalysis
• autocatalytic mechanism