Journal of Materials Research and Technology (Nov 2024)

On the novel precipitation sequence of the TiN modified Al-Mn-Sc alloy processed by laser powder bed fusion

  • Hao Tang,
  • Zhiyu Xiao,
  • Chaofeng Gao,
  • Zhiyuan Liu,
  • Xiaoying Xi,
  • Jiantao Zhang,
  • Boshen Weng,
  • Xingyi Li,
  • Yunjie Bi,
  • Jeremy Heng Rao

Journal volume & issue
Vol. 33
pp. 7788 – 7794

Abstract

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The influence of TiN addition on the new precipitation sequence and hardening effects of TiN modified Al-Mn-Sc alloy processed by LPBF was systematically studied in this work. The diffusion behavior of TiN particles results in obvious difference in the main alloying elements concentrations, altering the lattice constants of both primary and secondary L12-Al3(Ti,Sc,Zr) precipitates in the alloy matrix composite. After being subjected to peak-aging treatment, a novel precipitation sequence was observed in the sample containing 1.5 wt% TiN via generating a higher volume fraction of coherent L12-Al3Sc and semi-coherent rod-like Al6(Mn,Fe) precursors, corresponding to an alleviated internal strain as well. This new phenomenon has been demonstrated as a novel hardening mechanisms contributing to both microstructure refinement and mechanical property enhancement. As the results, the sample containing 1.5 wt% TiN exhibits an ultra-high yield strength of 651 ± 7 MPa and a compensate fracture elongation rate of 3.9 ± 0.3 %.

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