Cobalt Boride/g-C₃N₄ Nanosheets-Assisted Electrocatalytic Oxidation of 5-Hydroxymethylfurfural into 2,5-Furandicarboxylic Acid

Abstract

The electrochemical production of 2,5-furandicarboxylic acid (FDCA) from 5-(hydroxymethyl)furfural (HMF) is receiving growing attention. The FDCA-based polyethylene 2,5-furan dicarboxylate (PEF) polymer is a green candidate for substituting polyethylene terephthalate. This work demonstrated a highly efficient CoB/g-C3N4 nanosheet on the surface of the nickel foam as an electrode for the HMF electrooxidation reaction. Electrolysis at a constant potential combined with liquid chromatography showed the formation of FDCA with a yield of 97% with an excellent faradaic efficiency of near 95%. CoB/g-C3N4 achieved a current density of 20 mA cm−2 for HMF oxidation in 1.0 M KOH with 10 mM HMF at 1.37 V vs. RHE before the competing oxygen evolution reaction. The electrocatalyst was effectively reused up to three times without compromising efficiency. This work demonstrates a cheap and active electrocatalyst material for the electrochemical formation of FDCA from HMF and gives perception into the reaction mechanism.

Keywords

• 5-hydroxymethylfurfural
• electrosynthesis
• oxidation
• electrocatalyst
• FDCA