Acta Crystallographica Section E (Feb 2008)

Bis[(2-quinolyl)methanediol-κ2N,O](sulfato-κO)copper(II) dihydrate

  • Abilio J. F. N. Sobral,
  • Ana Matos Beja,
  • Manuela Ramos Silva,
  • Joana A. Silva,
  • Nuno D. Martins

DOI
https://doi.org/10.1107/S1600536808001980
Journal volume & issue
Vol. 64, no. 2
pp. m394 – m394

Abstract

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In the title compound, [Cu(SO4)(C10H9NO2)2]·2H2O, the CuII ion is chelated by two (2-quinolyl)methanediol ligands and coordinated by a monodentate sulfate ligand in a distorted trigonal–bipyramidal environment, with O atoms occupying the equatorial sites and N atoms in the axial sites. The dihedral angle between the two essentially planar quinoline ring systems is 45.02 (9)°. In the crystal structure, an extensive O—H...O hydrogen-bonding network forms layers parallel to the ab plane.