IUCrData (Apr 2019)

(R,R/S,S)-9-Benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dione

  • Craig M. Forsyth,
  • Zohreh Nazarian

DOI
https://doi.org/10.1107/S2414314619005200
Journal volume & issue
Vol. 4, no. 4
p. x190520

Abstract

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The title compound, C19H18N2O4, a rare example of a spirocyclic orthoamide, was synthesized by a double cyclization of a N-Boc protected sarcosine derivative. The crystal structure of the racemic (R,R/S,S) modification reveals two near-orthogonal five-membered heterocyclic ring systems, each in an envelope configuration.

Keywords