Molecules (Dec 2022)

Mechanisms Involved in the Modification of Textiles by Non-Equilibrium Plasma Treatment

  • Gregor Primc,
  • Rok Zaplotnik,
  • Alenka Vesel,
  • Miran Mozetič

DOI
https://doi.org/10.3390/molecules27249064
Journal volume & issue
Vol. 27, no. 24
p. 9064

Abstract

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Plasma methods are often employed for the desired wettability and soaking properties of polymeric textiles, but the exact mechanisms involved in plasma–textile interactions are yet to be discovered. This review presents the fundamentals of plasma penetration into textiles and illustrates mechanisms that lead to the appropriate surface finish of fibers inside the textile. The crucial relations are provided, and the different concepts of low-pressure and atmospheric-pressure discharges useful for the modification of textile’s properties are explained. The atmospheric-pressure plasma sustained in the form of numerous stochastical streamers will penetrate textiles of reasonable porosity, so the reactive species useful for the functionalization of fibers deep inside the textile will be created inside the textile. Low-pressure plasmas sustained at reasonable discharge power will not penetrate into the textile, so the depth of the modified textile is limited by the diffusion of reactive species. Since the charged particles neutralize on the textile surface, the neutral species will functionalize the fibers deep inside the textile when low-pressure plasma is chosen for the treatment of textiles.

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