{Bis[2-(diphenylphosphanyl)phenyl] ether-κ2P,P′}(1,1′-dibenzyl-1H,1′H-4,4′bi-1,2,3-triazole-κ2N3,N3′)copper(I) hexafluoridophosphate dichloromethane hemisolvate

Abstract

In the crystal structure of the title compound, [Cu(C18H16N6)(C36H28OP2)]PF6·0.5CH2Cl2 or [Cu(DPEPhos)(Bn-bta)]PF6·0.5CH2Cl2 {DPEPhos = bis[(diphenylphosphanyl)phenyl] ether and Bn-bta = 1,1′-dibenzyl-1H,1′H-4,4′-bi-1,2,3triazole}, the Cu atom is coordinated by two N and two P atoms of the ligands in a strongly distorted tetrahedral environment. There are two crystallographically independent complex cations present, which differ significantly in their geometrical parameters. The solvent molecule is disordered but satisfactory atomic positions could not be determined.