Acta Crystallographica Section E (Jan 2008)

N-(2-Chloroquinolin-3-ylmethylene)aniline

  • Rajesh G. Kalkhambkar,
  • Wen-Shu Hwang,
  • Geeta M. Kulkarni,
  • Chen-Shiang Lee

DOI
https://doi.org/10.1107/S1600536807064690
Journal volume & issue
Vol. 64, no. 1
pp. o258 – o258

Abstract

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The title compound, C16H11ClN2, displays a trans configuration across the C=N bond and a transoid arrangement across the quinoline ring and the azomethine C atom. This arrangement facilitates C—H...Cl interactions. The packing in the crystal structure is due to intermolecular C—H...π and Cl...π (3.52 and 3.84 Å) interactions. The dihedral angle between the least-squares planes of 2-chloroquinoline and phenylamine is 16.61 (2)°.