Hydrogen Bond-Directed Self-Assembly of a Novel Pyrene Derivative
Yang Yu,
Yuzhen Zhao,
Yongsheng Mi,
Fengmei Fang,
Huimin Zhang,
Zhun Guo,
Yang Zhao,
Dong Wang
Affiliations
Yang Yu
Xi’an Key Laboratory of Advanced Photo-Electronics Materials and Energy Conversion Device, School of Electronic Information, Xijing University, Xi’an 710123, China
Yuzhen Zhao
Xi’an Key Laboratory of Advanced Photo-Electronics Materials and Energy Conversion Device, School of Electronic Information, Xijing University, Xi’an 710123, China
Yongsheng Mi
Department of Materials Physics and Chemistry, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
Fengmei Fang
Yantai Xianhua Technology Group Co., Ltd., Yantai 264006, China
Huimin Zhang
Xi’an Key Laboratory of Advanced Photo-Electronics Materials and Energy Conversion Device, School of Electronic Information, Xijing University, Xi’an 710123, China
Zhun Guo
Xi’an Key Laboratory of Advanced Photo-Electronics Materials and Energy Conversion Device, School of Electronic Information, Xijing University, Xi’an 710123, China
Yang Zhao
Xi’an Key Laboratory of Advanced Photo-Electronics Materials and Energy Conversion Device, School of Electronic Information, Xijing University, Xi’an 710123, China
Dong Wang
Department of Materials Physics and Chemistry, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
A symmetrical pyrene derivative chemical structure was prepared by a classical synthetic method such as the Sonogashira cross-coupling reaction. The molecular structure of the product was characterised in detail by nuclear magnetic resonance (NMR), mass spectrometry (MS) and other methods. Furthermore, the optical properties of the novel products were studied by UV-vis and photoluminescence spectroscopy. The electrochemical properties of the molecules were fully characterised by comparison of electrochemical experiments and DFT simulation. Scanning electron microscope (SEM) observed that the product successfully formed a regular self-assembly structure. The product verifies the role of the molecular structure of the disc-mounted molecules on the optical and self-assembly properties, and is of reference value in the field of organic optoelectronic molecules
