Nature Communications (Dec 2016)
Atomic-level insights in optimizing reaction paths for hydroformylation reaction over Rh/CoO single-atom catalyst
- Liangbing Wang,
- Wenbo Zhang,
- Shenpeng Wang,
- Zehua Gao,
- Zhiheng Luo,
- Xu Wang,
- Rui Zeng,
- Aowen Li,
- Hongliang Li,
- Menglin Wang,
- Xusheng Zheng,
- Junfa Zhu,
- Wenhua Zhang,
- Chao Ma,
- Rui Si,
- Jie Zeng
Affiliations
- Liangbing Wang
- Department of Chemical Physics, Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences, Hefei Science Center & National Synchrotron Radiation Laboratory, University of Science and Technology of China
- Wenbo Zhang
- Department of Chemical Physics, Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences, Hefei Science Center & National Synchrotron Radiation Laboratory, University of Science and Technology of China
- Shenpeng Wang
- Department of Chemical Physics, Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences, Hefei Science Center & National Synchrotron Radiation Laboratory, University of Science and Technology of China
- Zehua Gao
- Department of Chemical Physics, Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences, Hefei Science Center & National Synchrotron Radiation Laboratory, University of Science and Technology of China
- Zhiheng Luo
- Department of Chemical Physics, Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences, Hefei Science Center & National Synchrotron Radiation Laboratory, University of Science and Technology of China
- Xu Wang
- Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences
- Rui Zeng
- Department of Chemical Physics, Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences, Hefei Science Center & National Synchrotron Radiation Laboratory, University of Science and Technology of China
- Aowen Li
- Department of Chemical Physics, Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences, Hefei Science Center & National Synchrotron Radiation Laboratory, University of Science and Technology of China
- Hongliang Li
- Department of Chemical Physics, Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences, Hefei Science Center & National Synchrotron Radiation Laboratory, University of Science and Technology of China
- Menglin Wang
- Department of Chemical Physics, Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences, Hefei Science Center & National Synchrotron Radiation Laboratory, University of Science and Technology of China
- Xusheng Zheng
- Department of Chemical Physics, Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences, Hefei Science Center & National Synchrotron Radiation Laboratory, University of Science and Technology of China
- Junfa Zhu
- Department of Chemical Physics, Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences, Hefei Science Center & National Synchrotron Radiation Laboratory, University of Science and Technology of China
- Wenhua Zhang
- Department of Chemical Physics, Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences, Hefei Science Center & National Synchrotron Radiation Laboratory, University of Science and Technology of China
- Chao Ma
- Department of Chemical Physics, Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences, Hefei Science Center & National Synchrotron Radiation Laboratory, University of Science and Technology of China
- Rui Si
- Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences
- Jie Zeng
- Department of Chemical Physics, Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Strongly-Coupled Quantum Matter Physics of Chinese Academy of Sciences, Hefei Science Center & National Synchrotron Radiation Laboratory, University of Science and Technology of China
- DOI
- https://doi.org/10.1038/ncomms14036
- Journal volume & issue
-
Vol. 7,
no. 1
pp. 1 – 8
Abstract
Despite the advantages of using heterogeneous catalysts, most successful rhodium hydrogenations are carried out with homogeneous catalysts. Here the authors report a supported single atom rhodium catalyst providing high activities and selectivities for propene hydroformylation.