Doped Epoxy Resins as an Alternative to Luminescent Optical Sensors

Abstract

The main objective of the study was to prepare and then subject to thorough analysis photosensitive materials to determine their usability as materials for the production of special polymer optical fibers. A comparison of the physicochemical properties of compositions containing commercially available fluorescein with compositions doped with 2.7-dihydroxy naphthalene with epichlorohydrin (2.7-NAF.EP) was made. The degree of copolymer conversion, which is one of the most important parameters confirming the effectiveness of the curing method, was calculated based on ATR-FT-IR spectra. Additionally, in order to check the processing capabilities of the obtained compositions, a thorough thermal and spectroscopic analysis was performed (the best method used for this purpose is the coupled analysis technique (TG-DSC-MS)). The obtained results indicate that the photoluminescent properties of the dopants used were not suppressed after their introduction into the matrix. Thermal and spectroscopic analysis allowed us to determine the polymerization conditions in which the physicochemical properties of the obtained materials are the best from the optical fiber-technology point of view.

Keywords

• polymer optical materials
• thermal and spectroscopy analysis
• luminescence