Gap Nanoantennas toward Molecular Plasmonic Devices

Abstract

Recently we have demonstrated that single fluorescent molecules can be used as non-perturbative vectorial probes of the local field. Here, we expand on such experiments exploiting fluorescence lifetime of single molecules to probe various types of gap nanoantennas. First, studies of the nanoantennas are carried out to evaluate the electric field. We then investigate hybrid systems composed by nanoantennas and randomly positioned fluorescent molecules. Finally, we present a fabrication scheme for the controlled placement of fluorescent molecules at welldefined positions with respect to the dimer nanoantenna, which is a more direct route to probe the local field in an a priori determined way.