Non-Enzymatic Electrochemical Sensor Based on Sliver Nanoparticle-Decorated Carbon Nanotubes

Abstract

The authors report a non-enzymatic electrochemical sensor based on a sliver nanoparticle-decorated carbon nanotube (AgNPs-MWCNT). Highly-dispersed AgNPs were loaded on the MWCNT surface though a simple and facile two-step method. The morphology, components, and the size of the AgNPs-MWCNT nanocomposite were characterized by transmission electron microscopy, X-ray diffraction, and ICP analysis. Benefitting from the synergistic effect between the AgNPs and MWCNT, the AgNPs-MWCNT nanocomposite exhibited high electrocatalytic activity for H2O2; the AgNPs-MWCNT electrochemical sensor was prepared by coating the AgNPs-MWCNT nanocomposite on a glassy carbon electrode, and it showed a fast and sensitive response to H2O2 with a linear range of 1 to 1000 μM. The detection limit was 0.38 μM (S/N = 3). The sensor was applied to detect H2O2 in spiked human blood serum samples with satisfactory results.

Keywords

• carbon nanotubes
• silver nanoparticles
• nonenzymatic
• sensor
• hydrogen peroxide