Nature Communications (Feb 2019)
Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond
- Fupin Liu,
- Georgios Velkos,
- Denis S. Krylov,
- Lukas Spree,
- Michal Zalibera,
- Rajyavardhan Ray,
- Nataliya A. Samoylova,
- Chia-Hsiang Chen,
- Marco Rosenkranz,
- Sandra Schiemenz,
- Frank Ziegs,
- Konstantin Nenkov,
- Aram Kostanyan,
- Thomas Greber,
- Anja U. B. Wolter,
- Manuel Richter,
- Bernd Büchner,
- Stanislav M. Avdoshenko,
- Alexey A. Popov
Affiliations
- Fupin Liu
- Leibniz Institute for Solid State and Materials Research (IFW Dresden)
- Georgios Velkos
- Leibniz Institute for Solid State and Materials Research (IFW Dresden)
- Denis S. Krylov
- Leibniz Institute for Solid State and Materials Research (IFW Dresden)
- Lukas Spree
- Leibniz Institute for Solid State and Materials Research (IFW Dresden)
- Michal Zalibera
- Institute of Physical Chemistry and Chemical Physics, Slovak University of Technology
- Rajyavardhan Ray
- Leibniz Institute for Solid State and Materials Research (IFW Dresden)
- Nataliya A. Samoylova
- Leibniz Institute for Solid State and Materials Research (IFW Dresden)
- Chia-Hsiang Chen
- Leibniz Institute for Solid State and Materials Research (IFW Dresden)
- Marco Rosenkranz
- Leibniz Institute for Solid State and Materials Research (IFW Dresden)
- Sandra Schiemenz
- Leibniz Institute for Solid State and Materials Research (IFW Dresden)
- Frank Ziegs
- Leibniz Institute for Solid State and Materials Research (IFW Dresden)
- Konstantin Nenkov
- Leibniz Institute for Solid State and Materials Research (IFW Dresden)
- Aram Kostanyan
- Physik-Institut der Universität Zürich
- Thomas Greber
- Physik-Institut der Universität Zürich
- Anja U. B. Wolter
- Leibniz Institute for Solid State and Materials Research (IFW Dresden)
- Manuel Richter
- Leibniz Institute for Solid State and Materials Research (IFW Dresden)
- Bernd Büchner
- Leibniz Institute for Solid State and Materials Research (IFW Dresden)
- Stanislav M. Avdoshenko
- Leibniz Institute for Solid State and Materials Research (IFW Dresden)
- Alexey A. Popov
- Leibniz Institute for Solid State and Materials Research (IFW Dresden)
- DOI
- https://doi.org/10.1038/s41467-019-08513-6
- Journal volume & issue
-
Vol. 10,
no. 1
pp. 1 – 11
Abstract
Dilanthanide complexes that possess radical bridges exhibit enhanced magnetic exchange coupling, affording molecular magnets with high blocking temperatures. Here, the authors explore a series of dilanthanide-encapsulated fullerenes where the radical bridge is taken to its limit and the role is played by a single unpaired electron.
