High-performance and stable AgSbTe2-based thermoelectric materials for near room temperature applications

Abstract

AgSbTe2-based ternary chalcogenides show excellent thermoelectric performance at low- and middle-temperature ranges, yet their practical applications are greatly limited by their intrinsic poor thermodynamic stability. In this work, we demonstrate that AgSbTe2-based ternary chalcogenides can be stabilized for service below their decomposition threshold. A series of AgxSb2-xTe3-x (x = 1.0, 0.9, 0.8 and 0.7) samples have been prepared by the melt-quenching method. Among them, phase pure Ag0.9Sb1.1Te2.1 is verified by comprehensive structural characterizations from macroscale by X-ray diffraction to microscale by energy-dispersive spectroscopy and then to sub-nanometer scale by atom probe tomography. This composition is further chosen for the stability investigation. The decomposition threshold of Ag0.9Sb1.1Te2.1 appears around 473 K. Below this temperature, the chemical compositions and thermoelectric properties are barely changed even after 720 h annealing at 473 K. The figure-of-merit (zT) value of Ag0.9Sb1.1Te2.1 below the decomposition threshold is very competitive for real applications even compared with Bi2Te3-based alloys. The average zT of Ag0.9Sb1.1Te2.1 at 300–473 K reaches 0.84, which is higher than most other thermoelectric materials in a similar temperature range, promising applications in miniaturized refrigeration and power generation near room temperature.