Copper heap leach residue aggregates in concrete: Properties and performance

Abstract

This study assesses the feasibility of using copper heap leach residue (CHLR) as a sustainable alternative to natural aggregates in concrete production. The CHLR possesses flaky-angular shape grains with rough surface texture and microcracks, crystalline silica of 51.6 %, 6.1 mg/g silt-clay with a median particle size of 4.3 mm, and it becomes suitable for the partial replacement of natural fine and coarse aggregates after removing 4.2 mg/g fines through 60-minute wash. Concrete containing 25–75 % CHLR aggregates met design slump and air content of 125±25 mm and 2±0.5 %, respectively, while also demonstrating a negligible 2.9 % reduction in fresh density and 2.8 % increase in compaction factor. Concrete containing 50 % CHLR as a partial replacement of natural coarse and fine aggregates achieved compressive strengths of 47.3 MPa and 45.1 MPa at 28 days, while the compressive strength of control mix was 46.7 MPa. The mechanical properties significantly declined at 75 % CHLR incorporated concretes. The BSE-EDS analysis highlighted improved interfacial transition zone for CHLR aggregates with minimal microcracks at early age compared to the natural aggregates but developed interfacial transition zone microcracks with prolonged curing leading to a decline in mechanical strength development.

Keywords

• Copper heap leach residue
• Low carbon concrete
• Methyl blue value
• Fresh properties
• Mechanical properties
• Microstructures