Green Processing and Synthesis (Apr 2021)

Continuous sulfonation of hexadecylbenzene in a microreactor

  • Xu Yiming,
  • Liu Suli,
  • Meng Weijun,
  • Yuan Hua,
  • Ma Weibao,
  • Sun Xiangqian,
  • Xu Jianhong,
  • Tan Bin,
  • Li Ping

DOI
https://doi.org/10.1515/gps-2021-0021
Journal volume & issue
Vol. 10, no. 1
pp. 219 – 229

Abstract

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Heavy alkyl benzene sulfonates are inexpensive surfactants that are extensively used as oil-displacing agents during tertiary oil recovery. Among these, C16–18 heavy alkyl benzene sulfonates possess an excellent ability to reduce the oil-water interface tension. In this study, hexadecylbenzene sulfonic acid (HBSA) was synthesised in a continuous stirred-tank microreactor using a continuous method with 1,2-dichloroethane (EDC) dilution. Post-sulfonation liquid SO3 solution was used as a sulfonating agent for hexadecylbenzene (HDB). The effects of reaction conditions, such as the SO3:HDB molar ratio, sulfonation temperature and sulfonation agent concentration, on the yield and purity of the product were investigated. Optimisation of the reaction process yielded high-quality HBSA samples with a purity exceeding 99 wt%. The continuous sulfonation process significantly enhanced the production and efficiency in the case of a considerably short residence time (10 s) in the reactor, without the need for aging. The results of this study demonstrate significant potential for application in industrial production.

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