In situ ligand synthesis affording a new Co(ii) MOF for photocatalytic application

Abstract

In situ disulfide bond formation affords a new flexible dicarboxylic acid ligand of 3,3′-dithiobisbenzoic acid (3,3′-H2DTBA), which assembled with Co(ii) ions under hydrothermal conditions, generating a novel metal–organic framework (MOF), namely, [Co(3,3′-DTBA)2(H2O)2]n (1). This compound is assembled from layered structures, featuring weak interlayer interactions that can reduce pore blockage through relative sliding. The results of photocatalytic experiment indicate that MOF 1 is a good semiconducting material and it can function as photocatalyst for degrading methylene blue under the ultraviolet light irradiation. Cyclic experiments demonstrated its good stability and long-lasting photocatalytic performance, indicating its potential application value.

Keywords

• hydrothermal conditions
• mof
• photocatalysis
• semiconducting material
• uv light irradiation