Study of Interactions between Titanium Dioxide Coating and Wood Cell Wall Ultrastructure
Petr Svora,
Sylwia Svorová Pawełkowicz,
Petra Ecorchard,
Jiří Plocek,
Alena Schieberová,
Zdeněk Prošek,
Petr Ptáček,
Jan Pošta,
Piotr Targowski,
Petr Kuklík,
Ivo Jakubec
Affiliations
Petr Svora
University Centre for Energy Efficient Buildings, Czech Technical University in Prague, 273 43 Buštěhrad, Czech Republic
Sylwia Svorová Pawełkowicz
Institute of Inorganic Chemistry of the Czech Academy of Sciences, 250 68 Husinec-Řež, Czech Republic
Petra Ecorchard
Institute of Inorganic Chemistry of the Czech Academy of Sciences, 250 68 Husinec-Řež, Czech Republic
Jiří Plocek
Institute of Inorganic Chemistry of the Czech Academy of Sciences, 250 68 Husinec-Řež, Czech Republic
Alena Schieberová
Department of Chemistry and Chemical Technologies, Faculty of Wood Sciences and Technology, Technical University in Zvolen, T.G. Masaryka 24, 960 53 Zvolen, Slovakia
Zdeněk Prošek
University Centre for Energy Efficient Buildings, Czech Technical University in Prague, 273 43 Buštěhrad, Czech Republic
Petr Ptáček
University Centre for Energy Efficient Buildings, Czech Technical University in Prague, 273 43 Buštěhrad, Czech Republic
Jan Pošta
University Centre for Energy Efficient Buildings, Czech Technical University in Prague, 273 43 Buštěhrad, Czech Republic
Piotr Targowski
Institute of Physics, Faculty of Physics, Astronomy and Informatics, Nicolaus Copernicus University in Toruń, Grudziądzka 5, 87-100 Torun, Poland
Petr Kuklík
University Centre for Energy Efficient Buildings, Czech Technical University in Prague, 273 43 Buštěhrad, Czech Republic
Ivo Jakubec
Institute of Inorganic Chemistry of the Czech Academy of Sciences, 250 68 Husinec-Řež, Czech Republic
Titanium dioxide (TiO2) is used as a UV light absorber to protect wood matter from photodegradation. In this paper, interactions between wood and TiO2 coating are studied, and the efficiency of the coating is evaluated. For the experiments, two wood species were chosen: beech (Fagus sylvatica) and pine (Pinus sylvestris). Molecular and physical modifications in coated and uncoated wood exposed to UV radiation were investigated with Fourier transform infrared spectroscopy with attenuated total reflectance (FTIR-ATR) and transmission electron microscopy (TEM). UV-VIS spectroscopy was used to describe the absorption of UV light by the TiO2 planar particles chosen for the experiment. It was demonstrated that TiO2 coating protects wood against photodegradation to a limited extent. TEM micrographs showed fissures in the wood matter around clusters of TiO2 particles in beech wood.