Catalytic Activity of Thermolyzed [Co(NH<sub>3</sub>)<sub>6</sub>][Fe(CN)<sub>6</sub>] in CO Hydrogenation Reaction
Alevtina N. Gosteva,
Mayya V. Kulikova,
Yulya P. Semushina,
Mariya V. Chudakova,
Nikita S. Tsvetov,
Vasilii V. Semushin
Affiliations
Alevtina N. Gosteva
I.V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials—Subdivision of the Federal Research Centre «Kola Science Centre of the Russian Academy of Sciences» Science Centre of Russian Academy of Sciences, «Academic town», 26a., Apatity, 184209 Murmansk, Russia
Mayya V. Kulikova
A.V. Topchiev Institute of Petrochemical Synthesis, RAS, Leninsky prospect, 29, 119991 Moscow, Russia
Yulya P. Semushina
I.V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials—Subdivision of the Federal Research Centre «Kola Science Centre of the Russian Academy of Sciences» Science Centre of Russian Academy of Sciences, «Academic town», 26a., Apatity, 184209 Murmansk, Russia
Mariya V. Chudakova
A.V. Topchiev Institute of Petrochemical Synthesis, RAS, Leninsky prospect, 29, 119991 Moscow, Russia
Nikita S. Tsvetov
I.V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials—Subdivision of the Federal Research Centre «Kola Science Centre of the Russian Academy of Sciences» Science Centre of Russian Academy of Sciences, «Academic town», 26a., Apatity, 184209 Murmansk, Russia
Vasilii V. Semushin
I.V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials—Subdivision of the Federal Research Centre «Kola Science Centre of the Russian Academy of Sciences» Science Centre of Russian Academy of Sciences, «Academic town», 26a., Apatity, 184209 Murmansk, Russia
Currently, the processes of obtaining synthetic liquid hydrocarbons and oxygenates are very relevant. Fischer-Tropsch synthesis (FTS) is the most important step in these processes. The products of thermal destruction in argon of the mixture [Co(NH3)6][Fe(CN)6] and Al(OH)3 were used as catalysts for CO hydrogenation. The resulting compositions were studied using powder X-ray diffraction, IR spectroscopy, elemental analysis, SEM micrographs. The specific surface area, pore and particle size distributions were determined. It was determined that the DCS-based catalysts were active in the high-temperature Fischer-Tropsch synthesis. The effect of aluminum in the catalyst composition on the distribution of reaction products was revealed.
