The Astrophysical Journal Letters (Jan 2023)
Hydrogen Isotopic Composition of Hydrous Minerals in Asteroid Ryugu
- Laurette Piani,
- Kazuhide Nagashima,
- Noriyuki Kawasaki,
- Naoya Sakamoto,
- Ken-ichi Bajo,
- Yoshinari Abe,
- Jérôme Aléon,
- Conel M. O’D. Alexander,
- Sachiko Amari,
- Yuri Amelin,
- Martin Bizzarro,
- Audrey Bouvier,
- Richard W. Carlson,
- Marc Chaussidon,
- Byeon-Gak Choi,
- Nicolas Dauphas,
- Andrew M. Davis,
- Tommaso Di Rocco,
- Wataru Fujiya,
- Ryota Fukai,
- Ikshu Gautam,
- Makiko K. Haba,
- Yuki Hibiya,
- Hiroshi Hidaka,
- Hisashi Homma,
- Peter Hoppe,
- Gary R. Huss,
- Kiyohiro Ichida,
- Tsuyoshi Iizuka,
- Trevor R. Ireland,
- Akira Ishikawa,
- Shoichi Itoh,
- Noriko T. Kita,
- Kouki Kitajima,
- Thorsten Kleine,
- Shintaro Komatani,
- Alexander N. Krot,
- Ming-Chang Liu,
- Yuki Masuda,
- Kevin D. McKeegan,
- Mayu Morita,
- Kazuko Motomura,
- Frédéric Moynier,
- Izumi Nakai,
- Ann Nguyen,
- Larry Nittler,
- Morihiko Onose,
- Andreas Pack,
- Changkun Park,
- Liping Qin,
- Sara S. Russell,
- Maria Schönbächler,
- Lauren Tafla,
- Haolan Tang,
- Kentaro Terada,
- Yasuko Terada,
- Tomohiro Usui,
- Sohei Wada,
- Meenakshi Wadhwa,
- Richard J. Walker,
- Katsuyuki Yamashita,
- Qing-Zhu Yin,
- Tetsuya Yokoyama,
- Shigekazu Yoneda,
- Edward D. Young,
- Hiroharu Yui,
- Ai-Cheng Zhang,
- Tomoki Nakamura,
- Hiroshi Naraoka,
- Ryuji Okazaki,
- Kanako Sakamoto,
- Hikaru Yabuta,
- Masanao Abe,
- Akiko Miyazaki,
- Aiko Nakato,
- Masahiro Nishimura,
- Tatsuaki Okada,
- Toru Yada,
- Kasumi Yogata,
- Satoru Nakazawa,
- Takanao Saiki,
- Satoshi Tanaka,
- Fuyuto Terui,
- Yuichi Tsuda,
- Sei-ichiro Watanabe,
- Makoto Yoshikawa,
- Shogo Tachibana,
- Hisayoshi Yurimoto
Affiliations
- Laurette Piani
- ORCiD
- Centre de Recherches Pétrographiques et Géochimiques, CNRS—Université de Lorraine ; F-54500 Nancy, France ; [email protected]
- Kazuhide Nagashima
- Hawai‘i Institute of Geophysics and Planetology, University of Hawai‘i at Mānoa ; Honolulu, HI 96822, USA
- Noriyuki Kawasaki
- Department of Natural History Sciences, Hokkaido University, Sapporo 060-0810, Japan
- Naoya Sakamoto
- ORCiD
- Isotope Imaging Laboratory, Creative Research Institution, Hokkaido University, Sapporo 001-0021, Japan
- Ken-ichi Bajo
- Department of Natural History Sciences, Hokkaido University, Sapporo 060-0810, Japan
- Yoshinari Abe
- Graduate School of Engineering Materials Science and Engineering, Tokyo Denki University, Tokyo 120-8551, Japan
- Jérôme Aléon
- Institut de Minéralogie, de Physique des Matériaux et de Cosmochimie, Sorbonne Université , Museum National d’Histoire Naturelle, CNRS UMR 7590, IRD; F-75005 Paris, France
- Conel M. O’D. Alexander
- ORCiD
- Earth and Planets Laboratory, Carnegie Institution for Science, Washington, DC, 20015, USA
- Sachiko Amari
- ORCiD
- McDonnell Center for the Space Sciences and Physics Department, Washington University, St. Louis, MO 63130, USA; Geochemical Research Center, The University of Tokyo , Tokyo, 113-0033, Japan
- Yuri Amelin
- Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, GD 510640, People's Republic of China
- Martin Bizzarro
- ORCiD
- Centre for Star and Planet Formation, GLOBE Institute, University of Copenhagen, Copenhagen, DK-1350, Denmark
- Audrey Bouvier
- ORCiD
- Bayerisches Geoinstitut, Universität Bayreuth, Bayreuth D-95447, Germany
- Richard W. Carlson
- ORCiD
- Earth and Planets Laboratory, Carnegie Institution for Science, Washington, DC, 20015, USA
- Marc Chaussidon
- ORCiD
- Université Paris Cité , Institut de physique du globe de Paris, CNRS, F-75005 Paris, France
- Byeon-Gak Choi
- Department of Earth Science Education, Seoul National University, Seoul 08826, Republic of Korea
- Nicolas Dauphas
- Department of the Geophysical Sciences and Enrico Fermi Institute, The University of Chicago, Chicago, IL 60637, USA
- Andrew M. Davis
- ORCiD
- Department of the Geophysical Sciences and Enrico Fermi Institute, The University of Chicago, Chicago, IL 60637, USA
- Tommaso Di Rocco
- Faculty of Geosciences and Geography, University of Göttingen, Göttingen, D-37077, Germany
- Wataru Fujiya
- ORCiD
- Faculty of Science, Ibaraki University, Mito 310-8512, Japan
- Ryota Fukai
- ORCiD
- ISAS/JSEC , JAXA, Sagamihara 252-5210, Japan
- Ikshu Gautam
- ORCiD
- Department of Earth and Planetary Sciences, Tokyo Institute of Technology, Tokyo 152-8551, Japan
- Makiko K. Haba
- Department of Earth and Planetary Sciences, Tokyo Institute of Technology, Tokyo 152-8551, Japan
- Yuki Hibiya
- ORCiD
- General Systems Studies, The University of Tokyo, Tokyo 153-0041, Japan
- Hiroshi Hidaka
- ORCiD
- Earth and Planetary Sciences, Nagoya University, Nagoya 464-8601, Japan
- Hisashi Homma
- ORCiD
- Osaka Application Laboratory , SBUWDX, Rigaku Corporation, Osaka 569-1146, Japan
- Peter Hoppe
- ORCiD
- Max Planck Institute for Chemistry, Mainz D-55128, Germany
- Gary R. Huss
- ORCiD
- Hawai‘i Institute of Geophysics and Planetology, University of Hawai‘i at Mānoa ; Honolulu, HI 96822, USA
- Kiyohiro Ichida
- Analytical Technology, Horiba Techno Service Co., Ltd., Kyoto 601-8125, Japan
- Tsuyoshi Iizuka
- ORCiD
- Earth and Planetary Science, The University of Tokyo, Tokyo 113-0033, Japan
- Trevor R. Ireland
- School of Earth and Environmental Sciences, The University of Queensland, St Lucia QLD 4072, Australia
- Akira Ishikawa
- ORCiD
- Department of Earth and Planetary Sciences, Tokyo Institute of Technology, Tokyo 152-8551, Japan
- Shoichi Itoh
- Division of Earth and Planetary Sciences, Kyoto University, Kitashirakawaoiwake-cho, Sakyo-ku, Kyoto 606-8502, Japan
- Noriko T. Kita
- Geoscience, University of Wisconsin-Madison Madison, WI 53706, USA
- Kouki Kitajima
- ORCiD
- Geoscience, University of Wisconsin-Madison Madison, WI 53706, USA
- Thorsten Kleine
- Max Planck Institute for Solar System Research, D-37077 Göttingen, Germany
- Shintaro Komatani
- Analytical Technology, Horiba Techno Service Co., Ltd., Kyoto 601-8125, Japan
- Alexander N. Krot
- Hawai‘i Institute of Geophysics and Planetology, University of Hawai‘i at Mānoa ; Honolulu, HI 96822, USA
- Ming-Chang Liu
- Earth, Planetary, and Space Sciences, UCLA, Los Angeles, CA 90095, USA
- Yuki Masuda
- ORCiD
- Department of Earth and Planetary Sciences, Tokyo Institute of Technology, Tokyo 152-8551, Japan
- Kevin D. McKeegan
- Earth, Planetary, and Space Sciences, UCLA, Los Angeles, CA 90095, USA
- Mayu Morita
- ORCiD
- Analytical Technology, Horiba Techno Service Co., Ltd., Kyoto 601-8125, Japan
- Kazuko Motomura
- ORCiD
- Thermal Analysis, Rigaku Corporation, Tokyo 196-8666, Japan
- Frédéric Moynier
- Université Paris Cité , Institut de physique du globe de Paris, CNRS, F-75005 Paris, France
- Izumi Nakai
- Applied Chemistry, Tokyo University of Science, Tokyo 162-8601, Japan
- Ann Nguyen
- ORCiD
- Astromaterials Research and Exploration Science, NASA Johnson Space Center, Houston, TX 77058, USA
- Larry Nittler
- Earth and Planets Laboratory, Carnegie Institution for Science, Washington, DC, 20015, USA
- Morihiko Onose
- Analytical Technology, Horiba Techno Service Co., Ltd., Kyoto 601-8125, Japan
- Andreas Pack
- Faculty of Geosciences and Geography, University of Göttingen, Göttingen, D-37077, Germany
- Changkun Park
- ORCiD
- Earth-System Sciences, Korea Polar Research Institute, Incheon 21990, Republic of Korea
- Liping Qin
- University of Science and Technology of China , School of Earth and Space Sciences, Anhui 230026, People's Republic of China
- Sara S. Russell
- Department of Earth Sciences, Natural History Museum, London, SW7 5BD, UK
- Maria Schönbächler
- ORCiD
- Institute for Geochemistry and Petrology , Department of Earth Sciences, ETH Zurich, Zurich, Switzerland
- Lauren Tafla
- ORCiD
- Earth, Planetary, and Space Sciences, UCLA, Los Angeles, CA 90095, USA
- Haolan Tang
- ORCiD
- Earth, Planetary, and Space Sciences, UCLA, Los Angeles, CA 90095, USA
- Kentaro Terada
- Earth and Space Science, Osaka University, Osaka 560-0043, Japan
- Yasuko Terada
- Spectroscopy and Imaging, Japan Synchrotron Radiation Research Institute, Hyogo 679-5198 Japan
- Tomohiro Usui
- Faculty of Science, Ibaraki University, Mito 310-8512, Japan
- Sohei Wada
- ORCiD
- Department of Natural History Sciences, Hokkaido University, Sapporo 060-0810, Japan
- Meenakshi Wadhwa
- ORCiD
- School of Earth and Space Exploration, Arizona State University, Tempe, AZ 85281, USA
- Richard J. Walker
- ORCiD
- Department of Geology, University of Maryland , College Park, MD 20742, USA
- Katsuyuki Yamashita
- Graduate School of Natural Science and Technology, Okayama University, Okayama 700-8530, Japan
- Qing-Zhu Yin
- ORCiD
- Earth and Planetary Sciences, University of California, Davis, CA 95616, USA
- Tetsuya Yokoyama
- ORCiD
- Department of Earth and Planetary Sciences, Tokyo Institute of Technology, Tokyo 152-8551, Japan
- Shigekazu Yoneda
- ORCiD
- Science and Engineering, National Museum of Nature and Science ; Tsukuba 305-0005, Japan
- Edward D. Young
- ORCiD
- Earth, Planetary, and Space Sciences, UCLA, Los Angeles, CA 90095, USA
- Hiroharu Yui
- Chemistry, Tokyo University of Science, Tokyo 162-8601, Japan
- Ai-Cheng Zhang
- ORCiD
- School of Earth Sciences and Engineering, Nanjing University, Nanjing 210023, People's Republic of China
- Tomoki Nakamura
- Department of Earth Science, Tohoku University, Sendai, 980-8578, Japan
- Hiroshi Naraoka
- ORCiD
- Department of Earth and Planetary Sciences, Kyushu University, Fukuoka 819-0395, Japan
- Ryuji Okazaki
- ORCiD
- Department of Earth and Planetary Sciences, Kyushu University, Fukuoka 819-0395, Japan
- Kanako Sakamoto
- ISAS/JSEC , JAXA, Sagamihara 252-5210, Japan
- Hikaru Yabuta
- Earth and Planetary Systems Science Program, Hiroshima University, Higashi-Hiroshima, 739-8526, Japan
- Masanao Abe
- ISAS/JSEC , JAXA, Sagamihara 252-5210, Japan
- Akiko Miyazaki
- ISAS/JSEC , JAXA, Sagamihara 252-5210, Japan
- Aiko Nakato
- ISAS/JSEC , JAXA, Sagamihara 252-5210, Japan
- Masahiro Nishimura
- ISAS/JSEC , JAXA, Sagamihara 252-5210, Japan
- Tatsuaki Okada
- ORCiD
- ISAS/JSEC , JAXA, Sagamihara 252-5210, Japan
- Toru Yada
- ORCiD
- ISAS/JSEC , JAXA, Sagamihara 252-5210, Japan
- Kasumi Yogata
- ISAS/JSEC , JAXA, Sagamihara 252-5210, Japan
- Satoru Nakazawa
- ORCiD
- ISAS/JSEC , JAXA, Sagamihara 252-5210, Japan
- Takanao Saiki
- ISAS/JSEC , JAXA, Sagamihara 252-5210, Japan
- Satoshi Tanaka
- ORCiD
- ISAS/JSEC , JAXA, Sagamihara 252-5210, Japan
- Fuyuto Terui
- Kanagawa Institute of Technology, Atsugi 243-0292, Japan
- Yuichi Tsuda
- ISAS/JSEC , JAXA, Sagamihara 252-5210, Japan
- Sei-ichiro Watanabe
- ORCiD
- Earth and Planetary Sciences, Nagoya University, Nagoya 464-8601, Japan
- Makoto Yoshikawa
- ORCiD
- ISAS/JSEC , JAXA, Sagamihara 252-5210, Japan
- Shogo Tachibana
- ORCiD
- UTokyo Organization for Planetary and Space Science, University of Tokyo, Tokyo 113-0033, Japan
- Hisayoshi Yurimoto
- ORCiD
- Department of Natural History Sciences, Hokkaido University, Sapporo 060-0810, Japan; Isotope Imaging Laboratory, Creative Research Institution, Hokkaido University, Sapporo 001-0021, Japan
- DOI
- https://doi.org/10.3847/2041-8213/acc393
- Journal volume & issue
-
Vol. 946,
no. 2
p. L43
Abstract
Rock fragments of the Cb-type asteroid Ryugu returned to Earth by the JAXA Hayabusa2 mission share mineralogical, chemical, and isotopic properties with the Ivuna-type (CI) carbonaceous chondrites. Similar to CI chondrites, these fragments underwent extensive aqueous alteration and consist predominantly of hydrous minerals likely formed in the presence of liquid water on the Ryugu parent asteroid. Here we present an in situ analytical survey performed by secondary ion mass spectrometry from which we have estimated the D/H ratio of Ryugu’s hydrous minerals, D/H _Ryugu , to be [165 ± 19] × 10 ^−6 , which corresponds to δ D _Ryugu = +59 ± 121‰ (2 σ ). The hydrous mineral D/H _Ryugu ’s values for the two sampling sites on Ryugu are similar; they are also similar to the estimated D/H ratio of hydrous minerals in the CI chondrites Orgueil and Alais. This result reinforces a link between Ryugu and CI chondrites and an inference that Ryugu’s samples, which avoided terrestrial contamination, are our best proxy to estimate the composition of water at the origin of hydrous minerals in CI-like material. Based on this data and recent literature studies, the contribution of CI chondrites to the hydrogen of Earth’s surficial reservoirs is evaluated to be ∼3%. We conclude that the water responsible for the alteration of Ryugu’s rocks was derived from water ice precursors inherited from the interstellar medium; the ice partially re-equilibrated its hydrogen with the nebular H _2 before being accreted on the Ryugu’s parent asteroid.
Keywords
- Carbonaceous chondrites
- Earth (planet)
- Asteroids
- Ice composition
- Solar system
- Small Solar System bodies
