Química Nova (Jan 2013)

The use of tribromoisocyanuric acid to distinguish among primary, secondary and tertiary alcohols

  • Lívia T. C. Crespo,
  • Marcio C. S. de Mattos,
  • Pierre M. Esteves

DOI
https://doi.org/10.1590/S0100-40422013000200019
Journal volume & issue
Vol. 36, no. 2
pp. 320 – 323

Abstract

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Primary, secondary and tertiary alcohols can be easily distinguished due to their reactivity towards tribromoisocyanuric acid (TBCA). The test is performed by adding TBCA to the alcohol in a test tube heated in a boiling water bath. Orange color develops in the tube containing the primary alcohol, light yellow is observed in the tube containing the secondary alcohol while the tertiary alcohol results in a colorless mixture.

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