Acta Crystallographica Section E (Jul 2008)

(1RS,4SR)-3-Dichloromethylene-1,4-dimethyl-2-oxabicyclo[2.2.2]oct-5-ene

  • Andrew J. Tyrrell,
  • George C. Feast,
  • Jeremy Robertson

DOI
https://doi.org/10.1107/S1600536808017248
Journal volume & issue
Vol. 64, no. 7
pp. o1261 – o1261

Abstract

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X-ray crystallography was used to confirm the structure of the enantio-enriched title compound, C10H12Cl2O, a bicylic enol ether. A bridged boat-like structure is adopted and the dichloromethylene C atom is positioned significantly removed from the core bicyclic unit. In the crystal structure, molecules pack to form sheets approximately perpendicular to the a and c axes.