Molecules (Sep 2013)

Click Reactions as a Key Step for an Efficient and Selective Synthesis of D-Xylose-Based ILs

  • Matthieu Courty,
  • Sandrine Bouquillon,
  • Albert Nguyen Van Nhien,
  • Sylvain Gatard,
  • Nadège Ferlin

DOI
https://doi.org/10.3390/molecules180911512
Journal volume & issue
Vol. 18, no. 9
pp. 11512 – 11525

Abstract

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D-Xylose-based ionic liquids have been prepared from D-xylose following a five steps reaction sequence, the key step being a click cycloaddition. These ionic liquids (ILs) have been characterized through classical analytical methods (IR, NMR, mass spectroscopy, elemental analysis) and their stability constants, Tg and Tdec, were also determined. Considering their properties and their hydrophilicity, these compounds could be alternative solvents for chemical applications under mild conditions.

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