Crystals (Mar 2025)

The Impact of GaN Crystal Growth on Ammonia Flow Dynamics in Ammonothermal Processes

  • Marek Zak,
  • Pawel Kempisty,
  • Boleslaw Lucznik,
  • Robert Kucharski,
  • Michal Bockowski

DOI
https://doi.org/10.3390/cryst15030261
Journal volume & issue
Vol. 15, no. 3
p. 261

Abstract

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A computational fluid dynamics simulation was developed for the growth zone of gallium nitride crystallized using the alkaline ammonothermal method, considering the geometry of the seed crystals and the installation setup. The model focuses on temperature and velocity distributions, revealing turbulent and transient flow characteristics. Significant findings include the effect of crystal thickness on temperature and velocity changes, as well as the relationship between temperature distribution and growth rate. The results indicate that transient variations in flow and thermal fields affect the uniformity of growth and structural quality of the crystals. The paper contributes to optimizing ammonothermal crystallization processes by addressing critical parameters such as turbulence, thermal mixing, and crystal geometry.

Keywords