Nature Communications (Apr 2023)
Br−/BrO−-mediated highly efficient photoelectrochemical epoxidation of alkenes on α-Fe2O3
Abstract
Alkene epoxidation, whose products are important intermediates for the manufacture of pharmaceuticals and epoxy resins, has attracted extensive attention. Unlike the conventional electrochemical Br−/Br2-mediated epoxidation, here the authors report a photoelectrochemical Br−/BrO−- mediated system to achieve efficient epoxidation performance on α-Fe2O3.