Highly Sensitive Aspartame Electrochemical Sensor in Beverages Sample Using Glassy Carbon Electrode Modified with Boron Doped Nanodiamond/ZnO Nanoparticles Composite

Abstract

This study reports an electrochemical sensor for detecting aspartame using square wave voltammetry (SWV) on ZnONP/BDDNP electrode. ZnONP/BDDNP was able to oxidize aspartame at a potential of 0.34 V in a phosphate buffer solution pH 2.0 with a current of 80.1 µA. The limit of detection (LOD) was found to be 0.07 µM, the limit of quantitation (LOQ) was 0.25 µM and sensitivity was 1.23 µA µM-1. The relative standard deviation (RSD) was 1.6%, less than 5% indicating that ZnONP/BDDNP has good precision. ZnONP/BDDNP showed better results compared with the BDDNP electrode. The developed method showed good linearity in the concentration range of 30-100 µM. This method was successfully applied to determine aspartame in beverage samples with a recovery range of 85-110%. This shows that ZnONP/BDDNP with the suggested method is potentially applied in practical used.

Keywords

• aspartame
• boron-doped diamond powder
• human & health
• metal oxide nanoparticles