Comparative Study of SnO₂ and ZnO Semiconductor Nanoparticles (Synthesized Using <i>Randia echinocarpa</i>) in the Photocatalytic Degradation of Organic Dyes

Abstract

Symmetry in nanomaterials is essential to know the behavior of their properties. In the present research, the photocatalytic properties of SnO2 and ZnO nanoparticles were compared for the degradation of the cationic dyes Methylene Blue (MB) and Rhodamine B (RB). The nanoparticles were obtained through a green synthesis process assisted by Randia echinocarpa extracts; they were then analyzed through Fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD) to characterize their structure. Transmission electron microscopy (TEM) was used to identify the morphology and disclose nanoparticle size, and the optical properties were studied through Ultraviolet–visible spectroscopy (UV–Vis). The results show that the synthesized SnO2 and ZnO nanomaterials have quasispherical morphologies with average sizes of 8–12 and 4–6 nm, cassiterite and wurtzite crystal phases, and band gap values of 3.5 and 3.8 eV, respectively. The photocatalytic activity yielded 100% degradation of the MB and RB dyes in 210 and 150 min, respectively. ZnO performed higher photocatalytic degradation of the cationic dyes than SnO2 due to a higher content of Randia echinocarpa extracts remaining after the green synthesis process.

Keywords

• green synthesis
• <i>Randia echinocarpa</i>
• photocatalysis
• cationic dyes