Size-dependent kinetics during non-equilibrium lithiation of nano-sized zinc ferrite

Abstract

Reducing particle size of electrode materials to nanoscale dimensions is believed responsible for their enhanced reaction kinetics and electrochemical performance. Here, the authors use in situ transmission electron microscopy to study the dynamic process of the spinel zinc ferrite nanoparticles as a function of size, finding that the intercalation reaction pathway changes below a critical particle size.