Undulation instabilities in cholesteric liquid crystals induced by anchoring transitions

Abstract

Cholesteric liquid crystals (CLCs) have a characteristic length scale given by the pitch of the twisted stacking of their constituent rodlike molecules. Under homeotropic anchoring conditions where the molecules prefer to orient perpendicular to an interface, cholesteric interfaces exhibit striped phases with stripe widths commensurate with the pitch. Conversely, planar anchoring conditions have the molecules remain in the plane of the interface so that the CLC twists perpendicular to it. Recent work [Tran, Lavrentovich, Durey, Darmon, Haase, Li, Lee, Stebe, Kamien, and Lopez-Leon, Phys. Rev. X 7, 041029 (2017)2160-330810.1103/PhysRevX.7.041029] shows that varying the anchoring conditions dramatically rearranges the CLC stripe pattern, exchanging defects in the stripe pattern with defects in the molecular orientation of the liquid-crystal molecules. We show with experiments and numerical simulations that the CLC stripes also undergo an undulation instability when we transition from homeotropic to planar anchoring conditions and vice versa. The undulation can be interpreted as a transient relaxation of the CLC resulting from a strain in the cholesteric layers due to a tilting pitch axis, with properties analogous to the classic Helfrich-Hurault instability. We focus on CLC shells in particular and show that the spherical topology of the shell also plays an important role in shaping the undulations.