Molecules
(Feb 2023)
Paired Electrolysis Enabled Cyanation of Diaryl Diselenides with KSCN Leading to Aryl Selenocyanates
Wei-Bao He,
Luo-Lin Tang,
Jun Jiang,
Xiao Li,
Xinhua Xu,
Tian-Bao Yang,
Wei-Min He
Affiliations
Wei-Bao He
College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
Luo-Lin Tang
College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
Jun Jiang
School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China
Xiao Li
School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China
Xinhua Xu
College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
Tian-Bao Yang
National Engineering Research Center of Low-Carbon Processing and Utilization of Forest Biomass, Nanjing Forestry University, Nanjing 210037, China
Wei-Min He
School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China
DOI
https://doi.org/10.3390/molecules28031397
Journal volume & issue
Vol. 28,
no. 3
Abstract
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The first example of paired electrolysis-enabled cyanation of diaryl diselenides, with KSCN as the green cyanating agent, has been developed. A broad range of aryl selenocyanates can be efficiently synthesized under chemical-oxidant- and additive-free, energy-saving and mild conditions.
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