Unveiling Bottled Water Perils: Investigating Phthalate Ester Acid Leaching from Bottled Water in Qatar’s Scorching Climes

Abstract

Plastic bottles have gained widespread popularity due to their durability, affordability, and recyclable nature. Phthalic acid esters (PAEs) are used as plasticizers in PET bottle production, which has raised concerns regarding their presence in the environment and potential adverse effects on health, including carcinogenic and endocrine-disrupting properties. PAEs can migrate from PET bottles into the contents, especially when exposed to high temperatures. This study is the first study in Qatar to determine the leaching of DBP, BBP, and DEHP in local PET drinking water bottles under different stressful thermal conditions. GC–MS is a susceptible instrument, and it is an ideal technique to detect and quantify PAEs in collected local plastic water bottles under different storage temperatures, namely at room temperature, 24 °C; 50 °C; and cyclic temperatures of 70 °C. The limits of detection for DBP, BBP, and DEHP were 0.09, 0.33, and 0.93 µg/L, respectively. Five local brands of PET bottles in Qatar were collected and stored under thermal conditions (24, 50, and 70 °C cyclic). Three kinds of leached PAEs, including dibutyl phthalate (DBP), Benzyl butyl phthalate (BBP), and Bis(2-ethylhexyl) phthalate (DEHP), were detected by GC–MS , ranging from 2.84 to 17.32, 1.16 to 21.35, and 0.01 to 19.59 ng/L, respectively. Significant differences were observed between room temperature 24 °C, 50 °C, and cyclic temperature for concentrations of DBP, BBP, and DEHP.

Keywords

• PET
• PAEs
• DEHP
• DBP
• BBP
• GC–MS